Conflict-Aware Active Automata Learning

Active automata learning algorithms cannot easily handle conflict in the observation data (different outputs observed for the same inputs). This inherent inability to recover after a conflict impairs their effective applicability in scenarios where noise is present or the system under learning is mutating. We propose the Conflict-Aware Active Automata Learning (C AL) framework to enable handling conflicting information during the learning process. The core idea is to consider the so-called observation tree as a first-class citizen in the learning process. Though this idea is explored in recent work, we take it to its full effect by enabling its use with any existing learner and minimizing the number of tests performed on the system under learning, specially in the face of conflicts. We evaluate C AL in a large set of benchmarks, covering over 30 different realistic targets, and over 18,000 different scenarios. The results of the evaluation show that C AL is a suitable alternative framework for closed-box learning that can better handle noise and mutations

Shelf-Ocean material exchange influencing the Atlantic chemical composition off NW Iberian margin since the last glaciation

Rivers are the main conduit of sediment to the shelf. The basin geology, the drainage area and the discharge rate are the major factors that determine their sediment load (Milliman and Syvistski, 1992). Besides suspended particles, dissolved components may also give some information on the eroded crust. Sr isotopes in carbonate shells of biological organisms have been used to study, in the geological record, the influence exerted by the chemical weathering of the continental crust on the seawater composition (Macdougall, 1991). In this work, Sr isotope ratios obtained in tests of foraminifera representing the last 40 ka are presented and discussed in the scope of the palaeogeographical evolution of NW Iberia. This work aims to present and discuss the results of Sr isotope analyses (performed, by TIMS, in the Isotope Geology Laboratory of the University of Aveiro) of tests of two species of foraminifera, from nine samples taken along the OMEX core KC 024-19 (181 cm; 42°08’98’’N, 10°29´96’’W, and 2765m), collected in the Galicia Bank area, off Galicia. Taking into account that Sr contained in the carbonate tests is usually considered as preserving the signature of the contemporaneous seawater, one planktonic species (Globigerina bulloides) and one benthic species (Cibicides wuellerstorfi) were selected in order to try to detect Sr isotope variations both through time and between two different levels of the water column. The core age model, which records the last 40 ka, is based on a combination of oxygen isotope stratigraphy, eight AMS 14C datings and the synchronisation of the last four Heinrich Events in the Iberian Margin sedimentary records. As a whole, the obtained 87Sr/86Sr ratios vary between 0.709209 and 0.709108, with a mean 2σ error of 0.000025. These values lie within the range of modern marine Sr isotope ratios (0.70910-0.70922), as previously defined using analyses of both seawater and marine carbonates (see compilation by Faure and Mensing, 2005). Despite their small variation, the 87Sr/86Sr ratios obtained in G. bulloides seem to indicate that Sr dissolved in seawater at the KC 024-19 core site became slightly less radiogenic after the Last Glacial Maximum (LGM). This decrease is concomitant with diminishing amounts of the detrital components in the sediments (Fig. 1). Therefore, both the composition of dissolved Sr, as revealed by results on tests of planktonic foraminifera, and the proportions of suspended terrigenous particulate material arriving at the KC 024-19 site point to a decreasing importance of the contribution of the erosion of the Iberian Variscan crust since the Last Glacial Maximum and in the Holocene. The 87Sr/86Sr ratios measured in tests of benthic foraminifera (C. wuellerstorfi) are more erratic and no correlation can be established with palaeogeographical/palaeoclimatic constraints. The difference between the behaviour of Sr compositions in G. bulloides and C. wuellerstorfi may indicate that whilst the planktonic foraminifera should reproduce very closely the seawater composition, the benthic organisms should, in addition to the major role of seawater, also be affected by some sort of interaction with the sediments. As such, planktonic foraminifera are probably more reliable indicators of seawater composition in studies involving very small periods and corresponding very slight variations of the 87Sr/86Sr ratios. Taking into account that G. bulloides is a common planktonic species (living mostly in the first 50m of the water column), whose tests seem to be in equilibrium with sea water composition, variations in its 87Sr/86Sr ratios can be related with changes in the chemical composition of the water of the Atlantic Ocean off NW Iberian Margin. The highest 87Sr/86Sr values are contemporaneous with a period of low sea level (about -140 m; Dias et al., 2000) during the LGM. According to Dias et al. (2000) at 18 ka BP the shoreline was close to the shelf break. The summital parts of the Gerês and Estrela mountains were covered by local glaciers and close to the coast freezing occurred frequently. The river catchments, which extended far to the shelf, received more rainfall due to a longer, compared to present day conditions, wet season, which promoted both physical and chemical weathering. Higher pluviosity combined with the effect of spring ice melting maintained high river discharge and consequently caused very important sediment supply to the coastal zone. The extremely narrow shelf was a very energetic environment due to sea bottom inclination and very limited long wave refraction. Therefore, at that time, a long wet season and very competent rivers should have caused important erosion of the Variscan basement in NW Iberia. Additionally, then, the shoreline was much closer to the KC 024-19 site. The combination of all these factors favoured an important deposition of terrigenous sediments and the local slight enrichment in radiogenic Sr of the seawater. With sea level rise, after the deglaciation and during the Holocene, the river estuaries became progressively far away from the shelf break. Their competence of transport also became progressively reduced and the offshore transport of detrital sediments became progressively lower. Conversely the biogenic carbonate proportion in the sediments increased, due to lower dilution by the terrigenous particles. Simultaneously, the values of 87Sr/86Sr in the seawater at the KC 024-19 site became lower, as a consequence of a complete homogenization with the ocean global composition, which was now more effective with the increasing distance towards shoreline

Seismic vulnerability assessment of the old city centre of Seixal, Portugal

The seismic vulnerability assessment of old traditional masonry building stocks, in a seismic risk mitigation perspective, is truly essential not only for buildings with recognized historical and patrimonial value, but also, in relation to regular buildings. In this sense, this paper approaches the issue of the seismic vulnerability assessment of masonry buildings through the application of a simplified methodology to building stock of the old city centre of Seixal, Portugal. This methodology is based on a vulnerability index, suitable in the evaluation of damage and in the creation of large scale loss scenarios (economical and human). Over 500 buildings were evaluated in accordance with the referred methodology and the results obtained were then integrated into a Geographical Information System tool. The integration of this kind of vulnerability and loss results into a GIS tool allows that city councils or regional authorities make their decisions based on a global view of the site under analysis, which led to more accurate and faster decisions either in terms of risk mitigation strategies or rehabilitation plans. This tool can also assumes great importance in the construction of safety and rescue plans

Vulnerability assessment of urban building stock: a hierarchic approach

In the last decades the evaluation of the seismic risk are of rising concern, considered essential in the activity and definition of strategy planning and urban management. The evaluation of the seismic vulnerability of the existent building stock in the perspective of the seismic risk mitigation should not be placed only in relation to the isolated buildings of relevant historical and cultural importance, but also, in relation to the agglomerate of buildings in urban centres. The chronological construction process frequently results in characteristic heterogeneity of masonry and wall connection quality. In addition, buildings do not constitute independent units given that they share the mid-walls with adjacent buildings and the façade walls are aligned. This way, as post-seismic observations proved, buildings do not have an independent structural behaviour, but they interact amongst themselves, mainly for horizontal actions and so the structural performance should be studied at the level of the aggregate and not only for each isolated building. In most cases, for masonry structures there is no need for sophisticated dynamic analyses for seismic resistance verification or vulnerability assessment. This is even more relevant when an assessment at the level of a city centre is pursued. In this work, the results of evaluation of the vulnerability will be presented in accordance to three proposed methodologies based on a vulnerability index that consequently allows the evaluation of damage and creation of loss scenarios (economical and human) not only at the level of the building and its façade walls but also at the level of the aggregates. It will be discussed and evaluated the application of the referred methodologies and its integration in an SIG platform

Fichas de inspecção e registo: gestão integrada de informação sobre o edificado antigo do Seixal

A inspecção constitui a primeira tarefa na avaliação da condição de um edifício, compreendendo desde logo a identificação e o registo das suas anomalias de carácter estrutural e não estrutural. No caso particular dos edifícios antigos, e devido ao desconhecimento generalizado das técnicas e materiais de construção tradicionais, estas acções de inspecção revelam-se frequentemente inadequadas, comprometendo desta forma a formulação de um diagnóstico assertivo e a eficiência de eventuais acções de reabilitação ou reforço. As fichas de inspecção e registo assumiram-se desde sempre como uma das primeiras opções no conjunto das ferramentas de avaliação e diagnóstico das construções existentes, tanto na inferência das suas condições de habitabilidade, como no apoio a acções de avaliação imobiliária e patrimonial a diferentes escalas. Neste artigo apresentam-se os resultados do desenvolvimento e aplicação de um conjunto de seis fichas de inspecção e diagnóstico, organizadas por elementos/componentes do edifício, a cerca de 500 edifícios antigos do Núcleo Urbano Antigo do Seixal, em Portugal. Os resultados são posteriormente tratados estatisticamente e utilizados na criação de uma base de dados incorporada numa ferramenta de gestão integrada num Sistema de Informação Geográfica (SIG) aplicável na gestão do edificado à escala urbana

Electron transfer driven decomposition of adenine and selected analogs as probed by experimental and theoretical methods

We report on a combined experimental and theoretical study of electron transfer induced decomposition of adenine and a selection of analogue molecules in collisions with potassium atoms (K). Time-of-flight negative ion mass spectra have been obtained in a wide collision energy range (6–68 eV in the centre-of-mass frame), providing a comprehensive investigation of the fragmentation patterns of purine, adenine, 9-methyl adenine, 6-dimethyl adenine and 2-D adenine. Following our recent communication about selective hydrogen loss from the transient negative ions (TNI) produced in these collisions [T. Dunha et al. J. Chem. Phys. 148, 021101 (2018)], this work focuses on the production of smaller fragment anions. In the low-energy part of the present range, several dissociation channels that are accessible in free electron attachment experiments are absent from the present mass spectra, notably NH2 loss from adenine and 9-methyl adenine. This can be understood in terms of a relatively long transit time of the K+ cation in the vicinity of the TNI tending to enhance the likelihood of intramolecular electron transfer. In this case, the excess energy can be redistributed through the available degrees of freedom inhibiting fragmentation pathways. Ab initio theoretical calculations were performed for 9-methyl adenine (9-mAd) and adenine (Ad) in the presence of a potassium atom and provided a strong basis for the assignment the lowest unoccupied molecular orbitals accessed in the collision process

Surface photochemistry: benzophenone as a probe for the study of silica and reversed-phase silica surfaces

This work reports the use of benzophenone, a very well characterized probe, to study new hosts: two reversed-phase silicas. Laser-induced room temperature luminescence of argon purged solid powdered samples of benzophenone adsorbed onto the two different reversed-phase silicas, RP-18 and RP-8, revealed the existence of a low energy emission band in contrast with the benzophenone adsorbed on 60 A pore silica, where only triplet benzophenone emits. This low energy emission band was identified as the fluorescence of the ketyl radical of benzophenone, which is formed as the result of a hydrogen atom abstraction reaction of the triplet excited benzophenone from the alkyl groups of the surface of the reversed silicas. Such emission does not exist for benzophenone adsorbed onto 60 A pore silica. Room temperature phosphorescence was obtained in argon purged samples for all the surfaces under use. The decay times of the benzophenone emission vary greatly with the alkylation of the silica surface when compared with "normal" silica surface. A lifetime distributions analysis has shown that the shortest lifetimes for the benzophenone emission exist in the former case. Triplet-triplet absorption of benzophenone was detected in all cases and is the predominant absorption in the case of 60 A pore silica, while benzophenone ketyl radical formation occurs in the case of the reversed silicas. Diffuse reflectance laser. ash photolysis and gas chromatography-mass spectrometry techniques provided complementary information, the former about transient species and the latter regarding the final products formed after laser irradiation, both at 266 nm or 355 nm. Product analysis and identification show that the degradation photoproducts are dependent on the excitation wavelength, the photochemistry being much more rich and complex in the 266 nm excitation case, where an alpha-cleavage reaction occurs. A detailed mechanistic analysis is proposed

Preservação de Xanthomonas axonopodis pv. Passiflorae em água de torneira esterilizada.

A preservação de culturas bacterianas é de suma importância para fins didáticos e experimentais. O presente trabalho teve como objetivo avaliar a viabilidade e a patogenicidade de dez isolados de Xanthomonas axonopodis pv. passiflorae preservados durante cinco anos em água de torneira esterilizada. Os isolados foram repicados para o meio de cultura 523 pelo método de estrias paralelas e incubados por 48 horas a 28ºC. As avaliações foram realizadas, observando-se a ocorrência ou não do crescimento bacteriano. Para avaliar a patogenicidade dos isolados, as plantas foram inoculadas através do método de corte com tesoura previamente imersa na suspensão bacteriana (108 UFC mL-1). A avaliação da incidência da doença foi realizada 5 dias após a inoculação. Todos os isolados de X. axonopodis pv. passiflorae cresceram em meio de cultura e foram patogênicos as plantas de maracujá inoculadas. A preservação em água de torneira esterilizada por cinco anos manteve a viabilidade e a patogenicidade de isolados de X. axonopodis pv. passiflorae